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자료유형
학술저널
저자정보
김지현 (고등기술연구원) 김진호 (고등기술연구원) 김효식 (고등기술연구원) 류재홍 (고등기술연구원) 강석환 (고등기술연구원) 이예지 (경북대학교) 이수출 (경북대학교)
저널정보
한국에너지기후변화학회 에너지기후변화학회지 에너지기후변화학회지 Vol.15 No.2
발행연도
2020.12
수록면
142 - 153 (12page)

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초록· 키워드

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Combustion characteristics of fuel oils such as bio heavy oil, pyrolysis oil, and ion refined oil were investigated to reserve basic data in terms of designing a reactor using fuel oil and selecting operating conditions. For the analysis of combustion characteristics, fuel oil was combusted with a thermogravimetric analyzer (TGA) under non-isothermal heating conditions (5 °C/min, 10 °C/min, 20 °C/min) in the air within the range of 25 °C to 945 °C. The activation energy and reaction order for fuel oil combustion have been kinetically interpreted using various methods such as the Kissinger, Chatterjee-Conrad, Coats-Redfern or Freeman-Carroll method. In this study, the activation energy of the three fuel oils was less than 50 kJ/mol, and Kissinger"s method with a reaction order of 1 showed an activation energy of less than 7.5. As a result, the activation energy and reaction order for the combustion characteristics of the three fuel oils were obtained for Freeman-Carroll"s method among several interpretation methods. Through this, the Freeman-Carroll method was commonly applied according to the type of fuel oil (bio heavy oil, pyrolysis oil, ion refined oil), and the Kissinger method was limited to pyrolysis oil within a certain range. Through this study, it was possible to classify an appropriate analysis method according to the type of fuel oil.

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ABSTRACT
1. 서론
2. 실험
3. 결과 및 고찰
4. 결론
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